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1.
Which has the greater N–O bond length, NO2 or NO3?

A)
NO2

B)
NO3

C)
The bond lengths are the same.

D)
More information is needed.

E)
None of these (A-D).


2.
Nitrous oxide (N2O, skeleton N-N-O) has three resonance structures. Based on an analysis of these three structures, including formal charges, the most likely N-N bond length is
Bond
average length
N-N
0.167 nm
N=N
0.120 nm
NN
0.110 nm

A)
0.110 nm

B)
0.112 nm

C)
0.120 nm

D)
0.136 nm

E)
0.167 nm


3.
The energy sequence of the molecular orbitals in OF is s2ss2s*s2pp2pp2p*s2p* . The cation OF1+ is predicted by simple molecular orbital theory to be __________ and _____________.

A)
unstable, diamagnetic

B)
unstable, paramagnetic

C)
stable, diamagnetic

D)
stable, paramagnetic


4.
The head-on, out of phase,  overlap of atomic p-orbitals in this fashion: yields the molecular orbital

A)
s

B)
s*

C)
p

D)
p*


5.
Consider a hypothetical molecule with the skeleton structure N-O-N.  In the most reasonable of the possible Lewis structures, the molecule has ______, and is likely to be ______.

A)
two double bonds, stable

B)
two double bonds, unstable

C)
a single bond and a triple bond, stable

D)
a single bond and a triple bond, unstable


6.
Which of the molecules below would you expect to have the highest boiling point?
 
        I                        II                         III                     IV
---------------------------------------------------------------------------------

A)
I

B)
II

C)
III

D)
IV

E)
II and IV


Use the following to answer questions 7-9:

Consider the molecule and the following hybridization choices:
                       H2N-N=CH-C≡CH
         atom #           1           2              3     


7.
What is the hybridization of the nitrogen atom that is single-bonded to nitrogen and two hydrogen atoms (#1)?

A)
sp

B)
sp2

C)
sp3

D)
dsp3

E)
d2sp3


8.
What is the hybridization of the carbon atom that is single bonded to hydrogen and triple bonded to carbon (#3)?

A)
sp

B)
sp2

C)
sp3

D)
dsp3

E)
d2sp3


9.
What is the hybridization of the carbon atom that is double bonded to nitrogen (#2)?

A)
sp

B)
sp2

C)
sp3

D)
dsp3

E)
d2sp3


10.
The energy sequence of the molecular orbitals in C2 is s2ss2s*p2ps2pp2p*s2p* .  The bond order for the C2-1 anion is

A)
0

B)
1

C)
1.5

D)
2

E)
2.5


Use the following to answer questions 11-12:

Draw the Lewis structures of the molecules below and use them to answer the following questions:
 I.
BH3
II.
NO2-1
III.
SF6
IV.
SO3
V.
PCl5



11.
Which of these molecules show resonance?

A)
I, II

B)
II, IV

C)
II, V

D)
III, IV

E)
III, V


12.
How many of the molecules have no dipole moment?

A)
1

B)
2

C)
3

D)
4

E)
They are all polar.


13.
In the molecular ion OF-1, the lone pair electrons on the fluorine are in

A)
p orbitals

B)
sp orbitals

C)
sp2 orbitals

D)
sp3 orbitals


14.
Which of the following ionic compounds has the smallest lattice energy (i.e., the lattice energy least favorable to a stable lattice)?

A)
LiF

B)
CsI

C)
NaCl

D)
BaO

E)
MgO


15.
The molecule H-N=N-H is __________ and the molecular cation H2N=O+ is _________.

A)
linear, planar

B)
planar, nonplanar

C)
nonplanar, planar

D)
planar, planar

E)
linear, nonplanar


16.
The in-phase sideways overlap of atomic p-orbitals leads to this molecular orbital:

A)
s

B)
s*

C)
p

D)
p*


17.
Consider the molecule ClF5.  The electronic geometry is __________ and the molecular geometry is __________.

A)
pentagonal, octahedral

B)
trigonal bipyramidal, trigonal bipyramidal

C)
octahedral, tetrahedral

D)
tetrahedral, trigonal pyramidal

E)
octahedral,  square pyramidal


18.
Which of the following has the smallest radius?

A)
F

B)
Ne

C)
O2–

D)
Mg2+

E)
Na+


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